Guoqi Zhang

Guoqi Zhang

Guoqi Zhang
Associate Professor
Phone number: 
212.621.3744
Room number and address: 
05.66.18NB

Education

Postdoc.       Los Alamos National Lab and University of Basel (2013)
Ph.D.             Institute of Chemistry, Chinese Academy of Science (2006)
B.S.                Wuhan University (2001)

Bio

Dr. Zhang earned his doctorate in Organic Chemistry from the Institute of Chemistry of Chinese Academy of Sciences in 2006. He then moved to the University of Basel in Switzerland and later to the Los Alamos National Laboratory (LANL) in the US to conduct postdoctoral research under the supervision of Professors Wolf-D Woggon, Catherine Housecroft and Edwin Constable, and Dr. Susan Hanson. He was a recipient of Novartis Foundation - Formerly the Ciba-Geigy Jubilee Foundation and LANL Director’s Postdoctoral Fellowships. Since 2013, he has been an Assistant Professor at John Jay College of the City University of New York (CUNY). He also holds a joint professorship at the CUNY Graduate Center. His research interests relate to drug discovery and synthesis, metal catalysis, metallosupramolecular chemistry and forensic chemistry.

Scholarly Work

Selected Publications:

Haisu Zeng, Jing Wu, Sihan Li, Christina Hui, Anita Ta, Shu-Yuan Cheng,* Shengping Zheng,* Guoqi Zhang,* “Copper(II)-Catalyzed Selective Hydroboration of Ketones and Aldehydes”, Org. Lett. 201921, 401-406.

Guoqi Zhang,* Jing Wu, Haisu Zeng, Michelle C. Neary, Matthew Devany, Shengping Zheng, Pavel A. Dub,* “Dearomatization and Functionalization of Terpyridine Ligands Leading to Unprecedented Zwitterionic Meisenheimer Aluminum Complexes and Their Use in Catalytic Hydroboration”, ACS Catal. 2019, 9, 874-884.

Guoqi Zhang,* Jing Wu, Sihan Li, Sean Cass, Shengping Zheng, “Markovnikov-Selective Hydroboration of Vinylarenes by a Cobalt(II) Coordination Polymer ”, Org. Lett. 2018, 20, 7893-7897.

Jing Wu, Haisu Zeng, Jessica Cheng, Shengping Zheng,* James A. Golen, David R. Manke, Guoqi Zhang,* “Cobalt(II) Coordination Polymer as a Precatalyst for Selective Hydroboration of Aldehydes, Ketones, and Imines”, J. Org. Chem. 2018, 83, 9442-9448.

Guoqi Zhang,* Jing Wu, Haisu Zeng, Shu Zhang, Zhiwei Yin, Shengping Zheng, “Cobalt-Catalyzed α-Alkylation of Ketones with Primary Alcohols”, Org. Lett. 2017, 19, 1080-1083.

Guoqi Zhang,* Haisu Zeng, Jing Wu, Zhiwei Yin, Shengping,* James C. Fettinger, “Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well-Defined Manganese Complex”, Angew. Chem. Int. Ed., 2016, 55, 14369-14372.

Zhiwei Yin, Haisu Zeng, Jing Wu, Shengping Zheng*, Guoqi Zhang,*  “Cobalt-Catalyzed Synthesis of Aromatic, Aliphatic, and Cyclic Secondary Amines via a ‘Hydrogen-Borrowing’ Strategy", ACS Catal. 20166, 6546-6550.

Guoqi Zhang,* Zhiwei Yin, Shengping Zheng, "Cobalt-catalyzed N-alkylation of amines with alcohols”, Org. Lett. 2016, 18, 300-303.

Zhang, G.;* Tan, J.; Zhang, Y.; Ta C.; Sanchez, S.; Cheng, S. -Y.;* Golen, J. A.; Rheingold, A. L., “Syntheses, structures and cytotoxicity of cobalt(II) complexes with 4’-chloro-2,2’:6’,2’’-terpyridine”, Inorg. Chim. Acta 2015, 435, 147-152.

Zhang, G.;* Liu, E.; Yang, C.; Li, L.; Golen, J. A.; Rheingold, A. L., “Copper(II) complexes of 2,2':6',2''-terpyridine derivatives for catalytic aerobic alcohol oxidations: observation of mixed-valence Cu(I)Cu(II) assembles”, Eur. J. Inorg. Chem. 2015, 939-947. 

Li, Q.; Xu, P.;* Gao, W.; Ma, S.; Zhang, G.;* Cao, R.; Cho, J.; Wang, H.; Wu, G.,* “Carbon-nanotubes/graphene nanocomposite derived from cage-containing metal-organic framework for oxygen reduction in nonaqueous Li-O2 battery cathodes”, Adv. Mater. 2014, 26, 1378-1386. 

Zhang, G.; Vasudevan, K. V.; Scott, B. L.; Hanson, S. K., “Understanding the mechanisms of cobalt-catalyzed hydrogenation and dehydrogenation reactions”, J. Am. Chem. Soc. 2013, 135, 8668-8681.

Zhang, G.; Scott, B. L.; Hanson, S. K., “Mild and homogeneous cobalt-catalyzed hydrogenation of C=C, C=O, and C=N bonds, Angew. Chem. Int. Ed. 2012, 51, 12102-12106. ("VIP" paper and Front Cover)

For a complete list of publications, please follow:

http://www.ncbi.nlm.nih.gov/sites/myncbi/1zUffandtbsQb/bibliography/48035559/public/?sort=date&direction=ascending

or

https://scholar.google.com/citations?user=Q5fOPWgAAAAJ&hl=en

 

Research Summary

I have extensive research interests in the area of synthetic chemistry of organic or metal-organic materials and their applications in drug synthesis, catalysis (homogeneous, heterogeneous and asymmetric), clean energy,  and forensic science. Current research in our laboratory concerns three aspects:

1)   Development of highly efficient catalyst systems based on earth-abundant metals (Co, Cu, Fe, Mn, V and Al)  towards green, atom-economic organic transformations and energy-related catalysis/electrocatalysis.

2)   Design, synthesis and cytotoxicity evaluation of novel metal-based anticancer agents using abundant and less toxic copper and cobalt.

3)    Multimetallic supramolecular chemistry and its applications in molecular recognition/sensing, catalysis and forensic science.

Students in our group will receive broad training in the areas of organic and organometallic synthesis, chemical catalysis and fluorescence analysis. They will gain hands-on working experience in modern synthetic techniques including Schlenk line and glovebox operations, and a variety of characterization and analytical techniques, including NMR spectroscopy, gas chromatography-mass spectrometry (GC-MS), high-performance liquid chromatography (HPLC), and FT-IR, UV-Vis and fluorescence spectroscopies.

Area of Expertise

Faculty Expertise: topics/keywords

 Organic Synthesis; Inorganic/Organometallic Catalysis; Inorganic Forensic Chemistry.

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